Product ID:AMERZINE CORROSION INHIBITOR
MSDS Date:01/21/1998
FSC:6810
NIIN:01-052-1651
MSDS Number: CJMVF

Emergency Phone: 800-325-3751

Info Phone: 614-790-3333

Preparer: THE MSDS CENTER

Cage: 34897

Telephone: 972-417-1288

Cage: 0WA27

HYDRAZINE (SARA 302/313) (CERCLA)

CAS: 302-01-2

RTECS: MU7175000

OSHA PEL S, 1 PPM

ACGIH TLV: S, 0.01 PPM, A3;9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: LIVER. EYES: CAN CAUSE
SEVERE IRRITATION. SKIN: CAN CAUSE IRRITATION & ALLERGIC SKIN
REACTION. PASSAGE THROUGH SKIN IS POSSIBLE. INGESTION: MAY BE
HARMFUL OR FATAL. MAY CAUSE BURNS & DESTROY TISSUE IN THE MOUTH,
THROAT, & DIGESTIVE TRACT. LOW BLOOD PRESSURE & SHOCK MAY OCCUR AS
A RESULT OF SEVERE TISSUE INJURY. INHALATION: BREATHING THIS
MATERIAL MAY BE HARMFUL OR FATAL. BREATH ING, SWALLOWING OR
PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY CAUSE CENTRAL NERVOUS
SYSTEM DEPRESSION, BLOOD ABNORMALITIES, KIDNEY DAMAGE, LIVER
DAMAGE, & CONVULSIONS.
Explanation of Carcinogenicity:HYDRAZINE HAS BEEN SHOWN TO CAUSE CANER
IN LABORATORY ANIMALS EXPOSED ORALLY, BY INHALATION OR BY INJECTION
INTO THE ABDOMEN. IT IS LISTED AS CARCINOGENIC BY IARC AND NTP.
Effects of Overexposure:EYES: STINGING, TEARING, REDNESS, SWELLING &
BLURRED VISION. SKIN: REDNESS & BURNING OF THE SKIN. MAY CAUSE
DELAYED SKIN RASH, BLISTERING, SCALING & OTHER SKIN EFFECTS.
INGESTION: MAY INCLUDE SEVERE NAUSEA, VOMITING, DIARRHEA,
ABDOMINAL PAIN, & VOMITING OF BLOOD. INHALATION: IRRITAITON &
BURNS TO THE NOSE, THROAT, & RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:LIVER.

First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES, HOLD LIDS OPEN. GET
MEDICAL ATTENTION. SKIN-WASH WITH SOAP & WATER. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. INHALED-REMOVE TO FRESH AIR. RESTORE
BREATHING AS N EEDED. GET MEDICAL ATTENTION. INGESTED-SEEK
IMMEDIATE MEDICAL ATTENTION; SEEK ADVICE ON WHETHER OR NOT TO
INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. DO NOT LEAVE
VICTIM UNATTENDED.

Lower Limits:4.7
Upper Limits:99.0
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP FIRE-EXPOSED
CONTAINERS COOL UNTIL FIRE IS OUT. WEAR A SELF-CONTAINED BREATHING
APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE DEMAND
MODE W/APPROPRIATE TURN-OUT GE AR & CHEMICAL RESISTANT PERSONAL
PROTECTIVE EQUIPMENT. REFER TO PERSONAL PROTECTIVE EQUIPMENT
SECTION OF THIS MSDS.
Unusual Fire/Explosion Hazard:FLAMMABLE AIR-VAPOR MIXTURE MAY
FORM-HYDRAZINE CAN IGNITE SPONTANEOUSLY WHEN DISPERSED IN AIR &
WHEN IN CONTACT WITH POROUS MATERIALS SUCH AS EARTH, WOOD, CLOTH
(RAGS SHOULD NEVER BE USED TO WIPE-UP S PILLS).

Spill Release Procedures:EVACUATE AREA. COVER WITH SODA ASH OR SODIUM
BICARBONATE. MIX & SPRAY WITH WATER. IF EFFERVESCENT, WAIT UNTIL
REACTION IS COMPLETE. SCOOP INTO CONTAINER. ELIMINATE ALL SOURCES
OF IGNITION. WEAR PROPER PPE. PREVENT SPILLS FROM ENTERING DRAINS,
SEWERS, STREAMS OR OTHER BODIES OF WATER. PUMP OR VACUUM TRANSFER
SPILLED PRODUCT TO CLEAN CONTAINERS FOR RECOVERY. ABSORB
UNRECOVERABLE PRODUCT.
Neutralizing Agent:SODA ASH, SODIUM BICARBONATE.

Handling and Storage Precautions:PRODUCT SHOULD BE STORED AT
TEMPERATURES WELL BELOW THEIR BOILING POINTS, AWAY FROM IGNITION
SOURCES AND OXIDANTS, AND PREFERABLY OUTDOORS. IT SHOULD BE
SHELTERED OUTDOORS AGAINST DIRECT SUNLIGHT.
Other Precautions:FOR INDOOR STORAGE AREAS, CONTINUOUS VENTILATION
SHOULD BE PROVIDED.

Respiratory Protection:WORKPLACE SHOULD BE MONITORED IF WORKER EXPOSED
TO VAPOR OR MISTS EXCEEDS PEL OR TLV. NIOSH/MSHA APPROVED
RESPIRATOR & CARTRIDGE (TC-23C) USAGE. MONITORING RESULTS TO
ASSESS PROPER LEVEL OF RESPIRATO RY PROTECTION NECESSARY(FULL FACE
PIECE RESPIRATOR W/CHEMICAL CARTRIDGES OR SELF-CONTAINED BREATHING
APPARATUS), MUST MEET REQUIREMENTS ESTAB 29 CFR 1910.134.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL)
EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:POLYVINYL CHLORIDE (PVC).
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD (8" MIN.) IN
COMPLIANCE W/OSHA REGS.
Other Protective Equipment:TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS
FULL-BODY PROTECTIVE CLOTHING. EYEWASH STATION.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR
INDUSTRIAL HYGIENIST.)

HCC:T4
Boiling Pt:=100.C, 212.F
B.P. Text:@760 MMHG FOR COMPONEN
Melt/Freeze Pt:=-13.9C, 7.F
Decomp Temp:Decomp Text:NONE PROVIDED BY MFR
Vapor Pres:17.5 @ 68F (COMPONENT)
Vapor Density:NOT APPLIC
Spec Gravity:1.012 @ 77 DEG F
pH:10.5 TO 11.5
Viscosity:NONE PROVIDED BY MFR
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NONE PROVIDED BY MFR
Appearance and Odor:CLEAR, WATER WHITE TO PALE YELLOW LIQUID. ODOR NOT
DETERMINED
Percent Volatiles by Volume:>95.0%
Corrosion Rate:NONE PROVIDED BY MFR

Stability Indicator/Materials to Avoid:YES
COPPER, COPPER ALLOYS, EXCESSIVE HEAT, LEAD, LEAD ALLOYS, ORGANIC
MATERIALS, STRONG MINERAL ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CARBON DIOXIDE, CARBON
MONOXIDE, NITROGEN COMPOUNDS.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.

Waste Disposal Methods:MIX WITH EQUAL VOLUME OF SODA ASH & WATER TO
FORM A SLURRY IN A LARGE CONTAINER. ADD CALCIUM HYPOCHLORITE, ADD
MORE WATER LET STAND 2 HRS, NEUTRALIZE AND WASH DOWN DRAIN. DISPOSE
OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Toxicological Information:NO DATA.

Ecological:NO DATA.

Transport Information:DOT DESCRIPTION: HYDRAZINE, AQUEOUS SOLUTIONS,
6.1, UN3293, III.

SARA Title III Information:SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A:
HYDRAZINE, TPQ = 1000 LBS, RQ = 1 LB. SECTION 311/312 HAZARD CLASS
- 40 CFR 370.2: IMMEDIATE & DELAYED. SARA 313 COMPONENTS - 40 CFR
372.65: HYDRAZINE, C AS# 302-01-2, 15.01%.
Federal Regulatory Information:LISTED ON THE TSCA INVENTORY LIST.
CERCLA REPORTABLE QUANTITY: 1 LB.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THE FOLLOWING
STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE
DRINKING WATER & TOXIC ENFORCEMENT ACT OF 1986; THIS PRODUCT
CONTAINS THE FOLLOWING SUBSTANCE(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: HYDRAZINE. NEW JERSEY RTK LABEL
INFORMATION: HYDRAZINE CAS# 302-01-2. PENNSYLVANIA RTK LABEL
INFORMATION: HYDRAZINE, CAS# 302-01-2.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.